One of the stated rules for Ryme City is "No Pokeballs" as the plan revolved ENTIRELY on the Pokémon breathing R, having Pokémon balls banned since the city's foundation means it's so much easier to get them to breathe it. The ban on battles could also fit into it: because people and Pokemon were going to want to fight anyway, driving it underground gave the villain a place where they could test substances like R, and people wouldn't take victims to the official medical system for fear of getting caught.

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